Soda Ash Characteristics

Soda ash, the trade name for sodium carbonate, is a chemical refined from the mineral trona. It is an essential raw material used in the manufacturing of glass, detergents chemicals, and other industrial products. There are two basic varieties of soda ash – natural soda ash and synthetic soda ash. Natural soda ash, regarded as the standard for quality and purity, is found in sodium-carbonate-bearing brines and mined from the earth. The Green River Basin of Wyoming is the world’s largest area for naturally-recurring trona. Synthetic soda ash is manufactured using a number of different chemical processes.

Soda ash is one of the most widely used and important commodities in the United States. Because so much soda ash is used by so many industries, monthly soda ash production data used by the Federal Reserve Board to monitor the condition of the U.S. economy.

When companies process and produce soda ash, a number of other sodium compounds are made as co-products, including sodium bicarbonate (also known as baking soda), sodium sulfite, sodium tripolyphosphate, and chemical caustic soda.

Product usage

Based on final 2005 reported data, the estimated 2006 distribution of soda ash by end use was

General chemical properties of soda ash


Chemical Name

Sodium Carbonate

Molecular Weight

105.989

Melting Point

851oC

1564oF

Specific Gravity, 20o/4oC

2.533

Specific Heat, 25oC

0.249 cal/gm/oC

                77oF

0.249 Btu/lb/oC

                45oC

0.256 cal/gm/oC


Heat of Fusion, 854oC

75.5 cal/gm

135.9 Btu/lb


Heat of Formation, 25oC

-2550 cal/gm

-4590 Btu/lb


Heat of Hydration

   Monohydrate, Na2CO3 • H2O

30.0 cal/gm Na2CO3

54.0 Btu/lb Na2CO3

   Heptahydrate, Na2CO3 • 7H2O

156.4 cal/gm Na2CO3

281.5 Btu/lb Na2CO3

   Decahydrate, Na2CO3 • 10H2O

208.8 cal/gm Na2CO3

 

375.8 Btu/lb Na2CO3

Solubility, 0oC

7 gms Na2CO3 in 100 gms H2O

           100oC

44.7 gms Na2CO3 in 100 gms H2O

           35.37oC (max.)

49.5 gms Na2CO3 in 100 gms H2O

Alkali equivalent

100 % Na2CO3 = 58.48 % Na2O

Acid equivalent

1 lb Na2CO3 = 0.6881 lb HCl




Sources: General Chemical Industrial Products
  Mineral Information Institute
  OCI Chemical Corporation
  U.S. Geological Survey